Aqua-{5,5′-dihydr-oxy-2,2′-[1,2-phenyl-ene-bis(nitrilo-methyl- idyne)]diphenolato-κ4 O,N,N′,O′}zinc(II) trihydrate

Naser Taha, Siang Guan Teoh, Suchada Chantrapromma, Hoong Kun Fun, Kamarulazizi Ibrahim

Research output: Contribution to journalJournal articlepeer-review

2 Scopus citations

Abstract

In the title complex, [Zn(C20H14N2O4)(H2O)]·3H2O, the Zn II center is in an approximately square-pyramidal coordination environment with the two N and two O atoms of the tetra-dentate Schiff base ligand forming the basal plane and the coordinated water mol-ecule in the apical position. Three solvent water mol-ecules complete the asymmetric unit. The dihedral angles between the two outer benzene rings of the Schiff base and the central benzene ring are 12.64 (14) and 17.25 (14)°. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into sheets parallel to the ab plane.

Original languageEnglish
Pages (from-to)m2838-m2839
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number11
DOIs
StatePublished - 5 Oct 2007
Externally publishedYes

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